Sequence Determination in Methyl Methacrylate–n-Butyl Methacrylate Copolymers by 13C NMR Spectroscopy
نویسندگان
چکیده
منابع مشابه
Statistical determination of chemical composition and monomer sequence distribution of poly(methyl methacrylate-co-tert-butyl methacrylate)s by multivariate analysis of 13C NMR spectra
To evaluate chemical compositions and heterogeneity of comonomer sequences in methyl methacrylate (MMA)-tert-butyl methacrylate (TBMA) copolymers, multivariate analysis was applied to the 13C nuclear magnetic resonance (NMR) spectra of the carbonyl, backbone quaternary and a-methyl carbons of the copolymers. A better linear relationship was found between the first principal component score and ...
متن کاملInvestigation of microstructure of glycidyl methacrylate/a-methyl styrene copolymers by 1D- and 2D-NMR spectroscopy
The copolymers of glycidyl methacrylate/a-methyl styrene were synthesized. The quantitative C{H}-NMR spectroscopy was used to determine the copolymer compositions. The distortionless enhancement by polarization transfer, C-H heteronuclear single quantum coherence and total correlation spectroscopy were used for the complete spectral assignment of C{H}and H-NMR spectra.
متن کاملSupramolecular interactions probed by 13C-13C solid-state NMR spectroscopy.
We present a robust solid-state NMR approach for the accurate determination of molecular interfaces in insoluble and noncrystalline protein-protein complexes. The method relies on the measurement of intermolecular (13)C-(13)C distances in mixtures of [1-(13)C]glucose- and [2-(13)C]glucose-labeled proteins. We have applied this method to Parkinson's disease-associated α-synuclein fibrils and fou...
متن کاملCalorimetric study of block-copolymers of poly(n-butyl acrylate) and gradient poly(n-butyl acrylate-co-methyl methacrylate)
The nanophase separation in diblock and triblock copolymers consisting of immiscible poly(n butyl acrylate) (block A) and gradient copolymers of methyl methacrylate (MMA) and n butyl acrylate (n BA) (block M/A) were investigated by means of their heat capacity, Cp, as a function of the composition of the blocks M/A and temperature. In all copolymers studied, both blocks are represented by their...
متن کاملStructural investigations of poly(methyl methacrylate) by two-dimensional NMR
In the present paper a comprehensive microstructure analysis of PMMA based on the combination of one-dimensional and twodimensional (TOCSY, HSQC, and HMBC) NMR experiments is reported. To resolve complex resonance assignments, empirical chemical shift modeling supported by the 2D NMR spectroscopy has been done. Rigorous assignments of resonance signals have been done by investigating the one bo...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Polymer Journal
سال: 1988
ISSN: 0032-3896,1349-0540
DOI: 10.1295/polymj.20.811